Urahara appears along with yoruichi to stop Aizen, Urahara had also prepared one of many tricks like special armor for Yoruichi to wear while facing Aizen. In that instant Urahara, Isshin, and Yoruichi go into intense battle against Aizen, since infused with the Hogyoku Aizen becomes more powerful by each second with him evolving more. While Ichigo is facing off against Gin leaving Rangiku running towards Gin.
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